Voici le programme des 16 matchs de groupe de la 4e journée de la ligue des champions Europe : 2012 -2013 .32 clubs européens s’affronteront entre le mardi 06/1/12 et le 07/10/12.
| 06/11/12 | -20h45 |  – |
Dynamo Kiev | Vs | FC Porto | |
| 06/11/12 | –20h45 | – |
PSG | Vs | Dinamo Zagreb | |
| 06/11/12 | –20h45 | – |
Schalke 04 | Vs | Arsenal | |
| 06/11/12 | –20h45 | – |
Olympiakos | Vs | Montpellier | |
| 06/11/12 | –20h45 | – |
Anderlecht | Vs | Zénith Saint-Pétersbourg | |
| 06/11/12 | –20h45 | – |
AC Milan | Vs | Malaga | |
| 06/11/12 | –20h45 | – |
Manchester City | Vs | Ajax Amsterdam | |
| 06/11/12 | –20h45 | – |
Real Madrid | Vs | Borussia Dortmund | |
| 07/11/12 | –20h45 | – |
Juventus Turin | Vs | Nordsjaelland | |
| 07/11/12 | –20h45 | – |
Chelsea | Vs | Shakhtar Donetsk | |
| 07/11/12 | –20h45 | – |
FC Valence | Vs | Bate Borisov | |
| 07/11/12 | –20h45 | – |
Bayern Munich | Vs | Lille | |
| 07/11/12 | –20h45 | – |
Benfica | Vs | Spartak Moscou | |
| 07/11/12 | –20h45 | – |
Celtic Glasgow | Vs | Barcelone | |
| 07/11/12 | –20h45 | – |
Cluj | Vs | Galatasaray | |
| 07/11/12 | –20h45 | – |
Braga | Vs | Manchester United | |